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Fouling mechanisms of submerged ultrafiltration membranes in greywater recycling

机译:灰水回收中超滤膜的结垢机理

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摘要

This study examined the influence of greywater constituents on the fouling behaviour of submerged\udhollow fibre UF membranes during greywater treatment for recycling purposes. Experiments were\udcarried out on a bench-scale equipment using a Zenon ZW1 module. The membrane was operated\udunder constant flux where an increase in transmembrane pressure was used to determine the extent\udof fouling. Wastewater constituent variables used in this study were kaolin, cellulose, humic acid,\udsurfactant, and calcium concentration. Results indicate that during filtration of synthetic greywater\udmultivalent ions like calcium played an important role. Depending on concentration agglomerates\udof different structure and size were formed and the structure and size determined the extent of\udfouling and retention. It was also shown that the surfactant sodium dodecyl sulphate (SDS) may\udcause fouling through particle stabilisation and strongly interacts with calcium enhancing calcium\udretention especially in the critical micelle concentration (cmc) region. It is hypothesized that SDS\udcompetes with humic acids (HAs) for adsorption sites resulting in lower UV254nm retention. Solution\udchemistry and cake deposition also influence the retention and hence product water quality.
机译:这项研究检查了灰水成分对灰水处理中被浸没的/空心纤维超滤膜结垢行为的影响,以进行回收利用。使用Zenon ZW1模块在台式规模的设备上进行实验。该膜在恒定通量下操作,其中跨膜压力的增加用于确定结垢程度。本研究中使用的废水成分变量是高岭土,纤维素,腐殖酸,表面活性剂和钙浓度。结果表明,在合成灰水\多价离子(如钙)的过滤过程中起着重要作用。取决于浓度,形成了不同结构和尺寸的附聚物\ ud,并且结构和尺寸决定了\污垢和保留的程度。还显示表面活性剂十二烷基硫酸钠(SDS)可能由于颗粒稳定化而结垢,并且与钙的强烈相互作用增强了钙的保留,特别是在临界胶束浓度(cmc)区域。据推测,SDS \与腐殖酸(HAs)竞争吸附位点会导致较低的UV254nm保留。溶液\化学反应和滤饼沉积也会影响保留率,进而影响产品水质。

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